Nanoscale bimetallic catalysts: are they really bimetallic?
L. Guczi, Dominique C. Bazin, Z. Schay, Imre Kovács
Abstract
L. Guczi, Dominique C. Bazin, Z. Schay, Imre Kovács
Abstract
Abstract The existence of bimetallic particles (and their reducibility and location on/or in the support) in Ru–Co/NaY and Pt–Co/NaY samples has been studied by in situ X‐ray adsorption spectroscopy (XAS). It is established that in Ru–Co/NaY the monometallic clusters maintain their identity, whereas in Pt–Co/NaY the existence of small bimetallic particles can be established. In both cases the results are supported by other techniques, such as XPS and temperature‐programmed reduction. Copyright © 2002 John Wiley & Sons, Ltd.
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Abstract The existence of bimetallic particles (and their reducibility and location on/or in the support) in Ru–Co/NaY and Pt–Co/NaY samples has been studied by in situ X‐ray adsorption spectroscopy (XAS). It is established that in Ru–Co/NaY the monometallic clusters maintain their identity, whereas in Pt–Co/NaY the existence of small bimetallic particles can be established. In both cases the results are supported by other techniques, such as XPS and temperature‐programmed reduction. Copyright © 2002 John Wiley & Sons, Ltd.
Key concepts: Bimetallic strip, X-ray absorption spectroscopy, X-ray photoelectron spectroscopy, Nanoscopic scale, Catalysis, Materials science, Adsorption, Chemical engineering