1980International Journal of Quantum ChemistryRequires access

Calculation of molecular electric polarizabilities and dipole moments. III. BH molecule

Carl E. Waltz, Hae‐Won Kim, Hendrik F. Hameka

Open publisher page 9 citations

Abstract

Abstract We use a previously proposed variation‐perturbation method to calculate the electric polarizabilities and the electric dipole moment at equilibrium nuclear distance of the BH molecule. We obtain 3.56 × 10−24 cm3 for the perpendicular polarizability αxx and 3.22 × 10−24 cm3 for the parallel polarizability αzz. Our result for the electric dipole moment μ0 is 1.734 debye units; there is no reliable experimental result to compare it with.

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What this paper is about

Abstract We use a previously proposed variation‐perturbation method to calculate the electric polarizabilities and the electric dipole moment at equilibrium nuclear distance of the BH molecule. We obtain 3.56 × 10−24 cm3 for the perpendicular polarizability αxx and 3.22 × 10−24 cm3 for the parallel polarizability αzz. Our result for the electric dipole moment μ0 is 1.734 debye units; there is no reliable experimental result to compare it with.

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Available abstract

Abstract We use a previously proposed variation‐perturbation method to calculate the electric polarizabilities and the electric dipole moment at equilibrium nuclear distance of the BH molecule. We obtain 3.56 × 10−24 cm3 for the perpendicular polarizability αxx and 3.22 × 10−24 cm3 for the parallel polarizability αzz. Our result for the electric dipole moment μ0 is 1.734 debye units; there is no reliable experimental result to compare it with.

Key concepts: Polarizability, Dipole, Electric dipole moment, Debye, Bond dipole moment, Moment (physics), Chemistry, Molecule

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