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Diastereospecific dihydroxylation and highly efficient asymmetric dihydroxylation kinetic resolution of cis/trans-2,6-dimethylbenzylidenecyclohexane

John M. Gardiner, Marck Nörret, Ian H. Sadler

Abstract

Achiral dihydroxylation and catalytic asymmetric dihydroxylation (AD) lead to reaction of only the cis(and not the trans) isomer of 2,6-dimethylbenzylidenecyclohexane, dihydroxylation is diastereoisomer specific and an efficient kinetic resolution is achieved using AD.

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Available abstract

Key concepts: Dihydroxylation, Kinetic resolution, Diastereomer, Chemistry, Stereochemistry, Resolution (logic), Catalysis, Enantioselective synthesis