Acetylation of aromatic ethers using acetic anhydride over solid acid catalysts in a solvent-free system. Scope of the reaction for substituted ethers
Keith Smith, Gamal Abdel-Rahman El-Hiti, Anthony J. Jayne, Michael Butters
Abstract
Keith Smith, Gamal Abdel-Rahman El-Hiti, Anthony J. Jayne, Michael Butters
Abstract
The acetylation of aryl ethers using acetic anhydride in the presence of zeolites under modest conditions in a solvent-free system gave the corresponding para-acetylated products in high yields. The zeolite can be recovered, regenerated and reused to give almost the same yield as that given when fresh zeolite is used.
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The acetylation of aryl ethers using acetic anhydride in the presence of zeolites under modest conditions in a solvent-free system gave the corresponding para-acetylated products in high yields. The zeolite can be recovered, regenerated and reused to give almost the same yield as that given when fresh zeolite is used.
Key concepts: Chemistry, Acetic anhydride, Acetylation, Yield (engineering), Catalysis, Organic chemistry, Acetic acid, Solvent