1996•Journal of the Chemical Society Perkin Transactions 1Requires access

Preparation and palladium-catalysed arylation of indolylzinc halides

Takao Sakamoto, Yoshinori Kondo, Nobuo Takazawa, Hiroshi Yamanaka

Abstract

Indolylzinc halides are prepared by two methods: transmetallation of indolyllithiums with zinc chloride and oxidative addition of active zinc to iodoindoles. The palladium-catalysed reaction of the indolylzinc halides provides a practical method for synthesizing arylindoles.

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Key concepts: Transmetalation, Halide, Palladium, Chemistry, Zinc, Oxidative addition, Chloride, Catalysis