2006•Angewandte Chemie International EditionRequires access

Electrophilicity–Nucleophilicity Scale Also in the Gas Phase

Chagit Denekamp, Yana Sandlers

Abstract

Changing the state: The electrophilicity of benzhydryl cations (see formula) towards neutral amine nucleophiles in the gas phase was determined. It was found that the kinetics of electrophile–nucleophile gas-phase reactions correlate well with values known in solution although the actual electrophilicity parameters are considerably smaller in the gas phase.

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Key concepts: Electrophile, Nucleophile, Gas phase, Chemistry, Amine gas treating, Kinetics, Phase (matter), Computational chemistry