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2001•Canadian Journal of ChemistryRequires access

Study of the hydroformylation of 2,5-dihydrofuran catalyzed by rhodium diphosphine complexes

Inmaculada del Rı́o, Piet W. N. M. van Leeuwen, Carmen Claver

Open publisher page 24 citations

Abstract

Rhodium diphosphine systems, including chiral ones, were used as catalyst precursors for the hydroformylation of 2,5-dihydrofuran. The effect of the reaction conditions and the bite angle on the activity and selectivity of the reaction were studied. The solution structures of the species present have been investigated spectroscopically through HP-NMR experiments during the hydroformylation reaction.Key words: hydroformylation, dihydrofuran, rhodium complexes, diphosphines, HP-NMR.

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What this paper is about

Rhodium diphosphine systems, including chiral ones, were used as catalyst precursors for the hydroformylation of 2,5-dihydrofuran. The effect of the reaction conditions and the bite angle on the activity and selectivity of the reaction were studied. The solution structures of the species present have been investigated spectroscopically through HP-NMR experiments during the hydroformylation reaction.Key words: hydroformylation, dihydrofuran, rhodium complexes, diphosphines, HP-NMR.

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Available abstract

Rhodium diphosphine systems, including chiral ones, were used as catalyst precursors for the hydroformylation of 2,5-dihydrofuran. The effect of the reaction conditions and the bite angle on the activity and selectivity of the reaction were studied. The solution structures of the species present have been investigated spectroscopically through HP-NMR experiments during the hydroformylation reaction.Key words: hydroformylation, dihydrofuran, rhodium complexes, diphosphines, HP-NMR.

Key concepts: Hydroformylation, Diphosphines, Rhodium, Chemistry, Catalysis, Selectivity, Organic chemistry, Medicinal chemistry

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