1993•Angewandte Chemie International Edition in EnglishRequires access
Highly Coordinated Lanthanoid–Phosphane Complexes
Hans H. Karsch, Gunter Ferazin, Oliver Steigelmann, H. Kooijman, Wolfgang Hiller
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Abstract
More and more lanthanoid–phosphorus bonds and a wide variety of structure variations are found in the complexes prepared from the phosphinomethanide Li[C(PMe2)2(SiMe3)] and lanthanoid triflates. In the homoleptic scandium complex 1, for example, the ligands are bound in a mode intermediate to σ and π coordination.