1999Journal of Dispersion Science and TechnologyRequires access

Adsorption of Methylene Blue on Montmorillonite

Guangming Chen, Jingjun Pan, Busing Han, Haike Yan

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Abstract

Adsorption of Methylene Blue ( MB) on Na-, Fe- and Al-montmorillonite suspensions at 298.15 K were studied. The effect of different exchangeable cation on the adsorption amount of MB was determined. The results show that methylene blue cations( MB+ ) replace Na∗ more easily than they do Fe3+ and Al3 + The adsorption isotherms on the three montraorillonites were all of Langmuir type, except that the isouHerm of MB on Na-montmorillonite presents nonmonotonic curve at low surface coverage. The specific surface areas in suspension were calculated by( MB 3 + )method, and Na− is more effective to determine the specific surface area by MB method in suspension than Fe3 + and A3 + The discrepancy of the specific surface area measured by MB and BET method was discussed.

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What this paper is about

Adsorption of Methylene Blue ( MB) on Na-, Fe- and Al-montmorillonite suspensions at 298.15 K were studied. The effect of different exchangeable cation on the adsorption amount of MB was determined. The results show that methylene blue cations( MB+ ) replace Na∗ more easily than they do Fe3+ and Al3 + The adsorption isotherms on the three montraorillonites were all of Langmuir type, except that the isouHerm of MB on Na-montmorillonite presents nonmonotonic curve at low surface coverage. The specific surface areas in suspension were calculated by( MB 3 + )method, and Na− is more effective to determine the specific surface area by MB method in suspension than Fe3 + and A3 + The discrepancy of the specific surface area measured by MB and BET method was discussed.

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Available abstract

Adsorption of Methylene Blue ( MB) on Na-, Fe- and Al-montmorillonite suspensions at 298.15 K were studied. The effect of different exchangeable cation on the adsorption amount of MB was determined. The results show that methylene blue cations( MB+ ) replace Na∗ more easily than they do Fe3+ and Al3 + The adsorption isotherms on the three montraorillonites were all of Langmuir type, except that the isouHerm of MB on Na-montmorillonite presents nonmonotonic curve at low surface coverage. The specific surface areas in suspension were calculated by( MB 3 + )method, and Na− is more effective to determine the specific surface area by MB method in suspension than Fe3 + and A3 + The discrepancy of the specific surface area measured by MB and BET method was discussed.

Key concepts: Adsorption, Montmorillonite, Methylene blue, Chemistry, Chemical engineering, Nuclear chemistry, Organic chemistry, Catalysis

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