A HIGHLY SELECTIVE AND RAPID SPECTROPHOTOMETRIC METHOD FOR THE DETERMINATION OF IRON(II) WITH 4-(2-THIAZOLYLAZO)RESORCINOL
Kazumasa Ueda, Yoshikazu Yamamoto
Abstract
Kazumasa Ueda, Yoshikazu Yamamoto
Abstract
Abstract 4-(2-Thiazolylazo)resorcinol reacts sensitively with iron(II) to form a water-soluble brown complex, which spectrally has the selective absorption at 730 nm. The absorbance is constant at pH 8.9 to 10.3 and Beer’s law holds up to 120 μg of iron(II). Many ions can be tolerable, especially 3d type metals. This method is comparable to that of 1,10-phenanthroline.
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Abstract 4-(2-Thiazolylazo)resorcinol reacts sensitively with iron(II) to form a water-soluble brown complex, which spectrally has the selective absorption at 730 nm. The absorbance is constant at pH 8.9 to 10.3 and Beer’s law holds up to 120 μg of iron(II). Many ions can be tolerable, especially 3d type metals. This method is comparable to that of 1,10-phenanthroline.
Key concepts: Chemistry, Resorcinol, Chromatography, Nuclear chemistry, Organic chemistry