Biotransformation of (-)-Dihydromyrcenol and (-)-Dihydromyrcenyl Acetate by the Larvae of Common Cutworm (Spodoptera litura).
Mitsuo Miyazawa, Takeshi Murata
Abstract
Mitsuo Miyazawa, Takeshi Murata
Abstract
(−)-Dihydromyrcenol and (−)-dihydromyrcenyl acetate were mixed in an artificial diet at a concentration of 1 mg/g of diet, and the diet was fed to the last instar larvae of common cutworm (Spodoptera litura). Metabolites were recovered from frass and analyzed spectroscopically. (−)-Dihydromyrcenol was transformed mainly to 1,2-epoxy dihydromyrcenol. (−)-Dihydromyrcenyl acetate was transformed mainly to 1,2-dihydroxydihydromyrcenyl acetate. The 1,2-doubule bonds of (−)-dihydromyrcenol and (−)-dihydromyrcenyl acetate were thus oxidized.
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(−)-Dihydromyrcenol and (−)-dihydromyrcenyl acetate were mixed in an artificial diet at a concentration of 1 mg/g of diet, and the diet was fed to the last instar larvae of common cutworm (Spodoptera litura). Metabolites were recovered from frass and analyzed spectroscopically. (−)-Dihydromyrcenol was transformed mainly to 1,2-epoxy dihydromyrcenol. (−)-Dihydromyrcenyl acetate was transformed mainly to 1,2-dihydroxydihydromyrcenyl acetate. The 1,2-doubule bonds of (−)-dihydromyrcenol and (−)-dihydromyrcenyl acetate were thus oxidized.
Key concepts: Spodoptera litura, Cutworm, Larva, Biotransformation, Chemistry, Noctuidae, Toxicology, Biology