1973Physical Review LettersRequires access

Measurements of the Rotational Viscosity Coefficient and the Shear-Alignment Angle in Nematic Liquid Crystals

S. Meiboom, R. C. Hewitt

Open publisher page 78 citations

Abstract

A method is described for the direct measurement of the shear-alignment angle in a nematic liquid crystal. Results of such measurements are reported for the nematic phases of three compounds: PAA ($p$, ${p}^{\ensuremath{'}}$-azoxydianisole), MBBA ($p$-methoxybenzylidene-${p}^{\ensuremath{'}}\ensuremath{-}n$-butylaniline), and HBAB ($p\ensuremath{-}n$-hexyloxybenzylidene-${p}^{\ensuremath{'}}$-aminobenzonitrile). We also report measurements of the rotational viscosity coefficient for the same compounds. In contrast to a recent report by G\"ahwiller, no orientational instability was found in HBAB.

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What this paper is about

A method is described for the direct measurement of the shear-alignment angle in a nematic liquid crystal. Results of such measurements are reported for the nematic phases of three compounds: PAA ($p$, ${p}^{\ensuremath{'}}$-azoxydianisole), MBBA ($p$-methoxybenzylidene-${p}^{\ensuremath{'}}\ensuremath{-}n$-butylaniline), and HBAB ($p\ensuremath{-}n$-hexyloxybenzylidene-${p}^{\ensuremath{'}}$-aminobenzonitrile). We also report measurements of the rotational viscosity coefficient for the same compounds. In contrast to a recent report by G\"ahwiller, no orientational instability was found in HBAB.

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Available abstract

A method is described for the direct measurement of the shear-alignment angle in a nematic liquid crystal. Results of such measurements are reported for the nematic phases of three compounds: PAA ($p$, ${p}^{\ensuremath{'}}$-azoxydianisole), MBBA ($p$-methoxybenzylidene-${p}^{\ensuremath{'}}\ensuremath{-}n$-butylaniline), and HBAB ($p\ensuremath{-}n$-hexyloxybenzylidene-${p}^{\ensuremath{'}}$-aminobenzonitrile). We also report measurements of the rotational viscosity coefficient for the same compounds. In contrast to a recent report by G\"ahwiller, no orientational instability was found in HBAB.

Key concepts: MBBA, Liquid crystal, Rotational viscosity, Materials science, Viscosity, Biaxial nematic, Condensed matter physics, Shear viscosity

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