2007•Journal of the American Chemical SocietyRequires access
Residual Dipolar Couplings by Off-Magic-Angle Spinning in Solid-State Nuclear Magnetic Resonance Spectroscopy
Giuseppe Pileio, Ying Guo, Tran Nghia Pham, John M. Griffin, Malcolm H. Levitt, Steven P. Brown
Open publisher page 46 citations
Abstract
A solid-state NMR analogue of the solution-state residual dipolar coupling effect is demonstrated. A small misset of the spinning axis by less than 0.5° changes the modulation frequency of spin−echoes, allowing the estimation of internuclear dipole−dipole couplings and hence internuclear distances.