Electron impact and chemical ionization mass spectra of aryl ureas
Joseph J. Brophy, Derek W. Nelson, James S. Shannon, Sydney Middleton
Abstract
Joseph J. Brophy, Derek W. Nelson, James S. Shannon, Sydney Middleton
Abstract
Abstract The electron impact and chemical ionization mass spectra of a series of N,N′, ‐diaryl ureas have been compared. The electron impact mass spectra indicate rearrangements leading to two pairs of aromatic amines and isocyanates, either as ions or molecules. The chemical ionization mass spectra showed the formation of protonated amines and isocyanates via rearrangement.
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Abstract The electron impact and chemical ionization mass spectra of a series of N,N′, ‐diaryl ureas have been compared. The electron impact mass spectra indicate rearrangements leading to two pairs of aromatic amines and isocyanates, either as ions or molecules. The chemical ionization mass spectra showed the formation of protonated amines and isocyanates via rearrangement.
Key concepts: Electron ionization, Mass spectrum, Chemical ionization, Chemistry, Protonation, Ionization, Molecule, Ion