1997•Fullerene Science and TechnologyRequires access

Synthesis and Characterisation of Some New Ferrocenyl- and Ferrocenylalkynyl-[60]Fullerene Compounds

David J. Cardin, Trevor Gibson, Jason A. Peel

Abstract

We report the synthesis and characterisation of a series of ferrocenylfullerene compounds, and some new ferrocene derivatives required as intermediates. The new fullerene species are Fc-[60]fullerene, (8); Fc-C[dbnd]C-[60]fullerene, (10); Fc-C[dbnd]C-C[dbnd]C-[60]fullerene, (12); and (η-C5H4SiBu3)Fe(η-C5H4)-[60]fullerene, (14).

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Key concepts: Fullerene, Ferrocene, Fullerene chemistry, Chemistry, Materials science, Nanotechnology, Electrochemistry, Organic chemistry