2010•Journal of the American Chemical SocietyRequires access

PbTiO3 Nanofibers with Edge-Shared TiO6 Octahedra

Zhaohui Ren, Gang Xu, Yong Liu, Xiao Wei, Yihan Zhu, Xiaobin Zhang, Guanglie Lv, Youwen Wang, Yuewu Zeng, Piyi Du, Wenjian Weng, Ge Shen, J.Z. Jiang, Gaorong Han

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Abstract

A new tetragonal phase of PbTiO(3) was discovered, in which each TiO(6) octahedron pair shares an edge and stacks over following pairs in an interlaced manner to form a one-dimensional (1D) columned structure along the c-axis. This new tetragonal phase of PbTiO(3) transforms into a normal perovskite phase in air at elevated temperature.

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Available abstract

Key concepts: Tetragonal crystal system, Octahedron, Chemistry, Perovskite (structure), Enhanced Data Rates for GSM Evolution, Phase (matter), Crystallography, Hydrothermal circulation