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2015•Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal ChemistryRequires access

Syntheses, Crystal Structure, and Properties of a New Co(II) Coordination Polymer Constructed from 1,10-Phenanthroline

Li Yang, Jing Guo, Chun Lian Zhang, Shu Hua Zhang

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Abstract

A new coordination polymer, {[Co(Phen)(HCOO)(H2O)Cl]·H2O]}n (1) (Phen = 1, 10-Phenanthroline), has been prepared by hydrothermal method and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 is orthorhombic, space group Pna21 with a = 19.0607(3) Å, b = 11.0557(2) Å, c = 6.5475(1) Å, V = 1379.75(4) Å3, Z = 4, Mr = 355.63, Dc = 1.712 g/cm3, F(000) = 724 and μ = 1.454 mm−1. X-ray diffraction analysis reveals that the title complex 1 displays a one-dimensional chain structure. Furthermore, the thermal stability and fluorescent properties of complex 1 were investigated.

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What this paper is about

A new coordination polymer, {[Co(Phen)(HCOO)(H2O)Cl]·H2O]}n (1) (Phen = 1, 10-Phenanthroline), has been prepared by hydrothermal method and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 is orthorhombic, space group Pna21 with a = 19.0607(3) Å, b = 11.0557(2) Å, c = 6.5475(1) Å, V = 1379.75(4) Å3, Z = 4, Mr = 355.63, Dc = 1.712 g/cm3, F(000) = 724 and μ = 1.454 mm−1. X-ray diffraction analysis reveals that the title complex 1 displays a one-dimensional chain structure. Furthermore, the thermal stability and fluorescent properties of complex 1 were investigated.

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Available abstract

A new coordination polymer, {[Co(Phen)(HCOO)(H2O)Cl]·H2O]}n (1) (Phen = 1, 10-Phenanthroline), has been prepared by hydrothermal method and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 is orthorhombic, space group Pna21 with a = 19.0607(3) Å, b = 11.0557(2) Å, c = 6.5475(1) Å, V = 1379.75(4) Å3, Z = 4, Mr = 355.63, Dc = 1.712 g/cm3, F(000) = 724 and μ = 1.454 mm−1. X-ray diffraction analysis reveals that the title complex 1 displays a one-dimensional chain structure. Furthermore, the thermal stability and fluorescent properties of complex 1 were investigated.

Key concepts: Orthorhombic crystal system, Phenanthroline, Coordination polymer, Crystallography, Crystal structure, Thermal stability, Hydrothermal circulation, Hydrothermal synthesis

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Syntheses, Crystal Structure, and Properties of a New Co(II) Coordination Polymer Constructed from 1,10-Phenanthroline — Research Paper | ScholarLens