Thermogravimetric Study on the Co-Pyrolysis Characteristics of Bituminous Coal and Wheat Straw
Xinping Yan, Ji Song Bai, Xiong Zhou, Shun Hong Lin
Abstract
Xinping Yan, Ji Song Bai, Xiong Zhou, Shun Hong Lin
Abstract
In this work, the pyrolysis behavior of bituminous coal (BC) wheat straw (WS) and the blends were investigated by thermogravimetric analysis. It was found that the main thermal degradation stage of BC and WS lies in different temperature range and there is nearly no overlapping. Interaction was observed during the co-pyrolysis process of BC and WS. At high temperatures, the volatile releasing is slightly inhibited by WS addition. Coats-Redfern method was used to analyze the apparent kinetic parameters. The results indicated that both the two reaction stages during pyrolysis process are well correlated by first-order reaction. The variation trend of activation energy value further confirm the synergistic effects between BC and WS. The experimental results may provide useful data for co-thermochemical utilization of biomass with coal.
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In this work, the pyrolysis behavior of bituminous coal (BC) wheat straw (WS) and the blends were investigated by thermogravimetric analysis. It was found that the main thermal degradation stage of BC and WS lies in different temperature range and there is nearly no overlapping. Interaction was observed during the co-pyrolysis process of BC and WS. At high temperatures, the volatile releasing is slightly inhibited by WS addition. Coats-Redfern method was used to analyze the apparent kinetic parameters. The results indicated that both the two reaction stages during pyrolysis process are well correlated by first-order reaction. The variation trend of activation energy value further confirm the synergistic effects between BC and WS. The experimental results may provide useful data for co-thermochemical utilization of biomass with coal.
Key concepts: Thermogravimetric analysis, Pyrolysis, Straw, Bituminous coal, Coal, Materials science, Activation energy, Biomass (ecology)