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A Comparative Study of the Influence of Protecting Groups on the Reactivity ofchiro-Inositol Glycosyl Acceptors

M. B. Cid, Manuel Martín‐Lomas, Francisco Alfonso

Abstract

The influence of protecting groups on the reactivity of glycosyl acceptors has been investigated through a series of competitive glycosylation experiments using differently substituted C2 symmetric d-chiro-inositol derivatives. It has been shown that, for a given glycosyl donor, the protective group pattern effectively modulates the reactivity of these derivatives in the glycosylation reaction.

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Available abstract

Key concepts: Chemistry, Glycosyl, Reactivity (psychology), Glycosylation, Glycosyl donor, Inositol, Protecting group, Stereochemistry