Effect of Viscosity Stabilizer on the Properties and Structure of Raw Constant Viscosity Rubber
Yong Zhou Wang, Ping Yue Wang, Bei Long Zhang, Honghai Huang, Li Ding, Fu Quan Zhang, Lei Fang, Ri Zhong Zeng
Abstract
Yong Zhou Wang, Ping Yue Wang, Bei Long Zhang, Honghai Huang, Li Ding, Fu Quan Zhang, Lei Fang, Ri Zhong Zeng
Abstract
The properties of raw constant viscosity natural rubber were measured using a rubber processing analyzer. The results show that the rubber processing analyzer can characterize well the effect of viscosity stabilizer on the dynamic mechanical properties of raw constant viscosity rubber by applied strain sweep or frequency sweep. In linear viscoelastic region, the increment of the dynamic torque S’ of the constant viscosity natural rubber prepared with hydroxylamine hydrochloride decreases with the increase in the level of hydroxylamine hydrochloride . In the range of low frequency, the increment of the dynamic modulus G’ of constant viscosity natural rubber prepared with hydroxylamine hydrochloride is obvious lower than those of natural rubber and constant viscosity natural rubber prepared with aniline. G’ of the constant viscosity natural rubber prepared with aniline is just only a little higher than that of natural rubber. Hydroxylamine hydrochloride and aniline can decrease the molecular weight of rubber, and change the molecular weight distribution. The dynamical properties of constant viscosity natural rubber are dependent on the molecular weight and the molecular weight distribution.
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The properties of raw constant viscosity natural rubber were measured using a rubber processing analyzer. The results show that the rubber processing analyzer can characterize well the effect of viscosity stabilizer on the dynamic mechanical properties of raw constant viscosity rubber by applied strain sweep or frequency sweep. In linear viscoelastic region, the increment of the dynamic torque S’ of the constant viscosity natural rubber prepared with hydroxylamine hydrochloride decreases with the increase in the level of hydroxylamine hydrochloride . In the range of low frequency, the increment of the dynamic modulus G’ of constant viscosity natural rubber prepared with hydroxylamine hydrochloride is obvious lower than those of natural rubber and constant viscosity natural rubber prepared with aniline. G’ of the constant viscosity natural rubber prepared with aniline is just only a little higher than that of natural rubber. Hydroxylamine hydrochloride and aniline can decrease the molecular weight of rubber, and change the molecular weight distribution. The dynamical properties of constant viscosity natural rubber are dependent on the molecular weight and the molecular weight distribution.
Key concepts: Natural rubber, Viscosity, Mooney viscosity, Materials science, Composite material, Polymer, Copolymer