2009•Chemical CommunicationsRequires access

Synthesis and structural characterisation of stable cationic gold(i) alkene complexes

Thomas N. Hooper, Michael Green, John E. McGrady, Jaynika R. Patel, Christopher A. Russell

Abstract

Treatment of [AuCl(PBu(t)(3))] with AgSbF(6) in CH(2)Cl(2) at room temperature in the presence of the alkenes norbornene, norbornadiene, trans-cyclooctene, and also interestingly, isobutylene, leads to the formation of stable crystalline complexes [Au(PBu(t)(3))(alkene)][SbF(6)], characterised by NMR spectroscopy and X-ray crystallography.

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Key concepts: Norbornene, Alkene, Norbornadiene, Cyclooctene, Cationic polymerization, Isobutylene, Chemistry, Nuclear magnetic resonance spectroscopy