1969•Journal of Polymer Science Part A-1 Polymer ChemistryRequires access

Polymers from 12‐hydroxymethyltetrahydroabietic acid and its vinyl and acrylate esters

Motoo Saga, C. S. Marvel

Abstract

Abstract 12‐Hydroxymethyltetrahydroabietic acid has been homopolymerized by melt condensation and homopolyester has been obtained. Vinyl 12‐hydroxymethyltetrahydroabietate has been prepared from 12‐hydroxymethyltetrahydroabietic acid by vinyl interchange procedure with vinyl acetate, and has been homopolymerized, copolymerized with vinyl chloride, vinyl acetate, and terpolymerized with styrene and acrylonitrile. The acrylate ester of 12‐hydroxymethyltetrahydroabietic acid also has been prepared from 12‐hydroxymethyltetrahydroabietic acid and acrylyl chloride. The acrylate thus obtained has been homopolymerized and copolymerized with vinyl chloride and vinyl acetate. Polymers thus obtained have been characterized.

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Key concepts: Vinyl acetate, Vinyl polymer, Vinyl chloride, Acrylonitrile, Acrylate, Styrene, Polymer chemistry, Methyl acrylate