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2011•New Journal of ChemistryRequires access

Thermodynamically controlled coordination-engineering of novel 2D cadmium thiolate coordination polymers

Nicolas Louvain, Yohei Takashima, Susumu Kitagawa, Shuhei Furukawa

Open publisher page 9 citations

Abstract

Reaction of Cd(OAc)2·2H2O with 4,4′-biphenyldithiol (H2bpdt) in different alkyldiamines at 105 °C gave single crystals of different 2D-layered cadmium thiolates metal–organic frameworks. The alkyldiamine acts both as a solvent and as a coordination-engineering agent to control the crystal growth and the dimensionality of the cadmium thiolate networks.

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What this paper is about

Reaction of Cd(OAc)2·2H2O with 4,4′-biphenyldithiol (H2bpdt) in different alkyldiamines at 105 °C gave single crystals of different 2D-layered cadmium thiolates metal–organic frameworks. The alkyldiamine acts both as a solvent and as a coordination-engineering agent to control the crystal growth and the dimensionality of the cadmium thiolate networks.

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OpenAlex reports 9 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

Reaction of Cd(OAc)2·2H2O with 4,4′-biphenyldithiol (H2bpdt) in different alkyldiamines at 105 °C gave single crystals of different 2D-layered cadmium thiolates metal–organic frameworks. The alkyldiamine acts both as a solvent and as a coordination-engineering agent to control the crystal growth and the dimensionality of the cadmium thiolate networks.

Key concepts: Chemistry, Cadmium, Coordination complex, Crystal engineering, Coordination polymer, Metal, Solvent, Metal-organic framework

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