ScholarLens Back to search
1981•Journal of the Chemical Society Chemical CommunicationsRequires access

First example of predominant β-orientation in electrophilic substitution of pyrrole

Maurizio Speranza

Open publisher page 14 citations

Abstract

The isomeric distribution of the neutral products from the gas-phase electrophilic attack of 3He3H+, CH3FCH3+, and t-C4H9+ ions on pyrrole provides the first experimental evidence for predominant β-orientation in electrophilic substitution of pyrrole [β : α N = 2·5 : 2·0 : 1·0(3He3H+); 1·4 : 0·4 : 1·0 (CH3FCH3+); 10·3 : 3·0 : 1·0 (t-C4H9+)].

About this research paper

What this paper is about

The isomeric distribution of the neutral products from the gas-phase electrophilic attack of 3He3H+, CH3FCH3+, and t-C4H9+ ions on pyrrole provides the first experimental evidence for predominant β-orientation in electrophilic substitution of pyrrole [β : α N = 2·5 : 2·0 : 1·0(3He3H+); 1·4 : 0·4 : 1·0 (CH3FCH3+); 10·3 : 3·0 : 1·0 (t-C4H9+)].

Why it matters

OpenAlex reports 14 citations for this work. Citation counts describe recorded attention and do not establish research quality.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

The isomeric distribution of the neutral products from the gas-phase electrophilic attack of 3He3H+, CH3FCH3+, and t-C4H9+ ions on pyrrole provides the first experimental evidence for predominant β-orientation in electrophilic substitution of pyrrole [β : α N = 2·5 : 2·0 : 1·0(3He3H+); 1·4 : 0·4 : 1·0 (CH3FCH3+); 10·3 : 3·0 : 1·0 (t-C4H9+)].

Key concepts: Pyrrole, Electrophile, Electrophilic substitution, Chemistry, Orientation (vector space), Substitution (logic), Ion, Substitution reaction

Related papers

Related paper 1Related paper 2Related paper 3
Back to paper searchBrowse research topicsOriginal source
First example of predominant β-orientation in electrophilic substitution of pyrrole — Research Paper | ScholarLens