1993Patai's chemistry of functional groupsRequires access

Electronic effects of ether and hydroxyl groups

John Shorter

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Abstract

This chapter contains sections titled: Introduction The Hammett Equation Substituent Effects on the Strengths of Carboxylic and Other Acids The Ortho-Effect The Cumulative Effects of Substituents Substituent Effects in Highly Electron-Demanding Reactions Electronic Effect of The Unipole O− The Impact of Modern Experimental and Theoretical Techniques on Substituent Constants Some Further Multiparameter Treatments of Substituent Effects Substituent Constants: Recapitulation and Some Extension References and Notes

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What this paper is about

This chapter contains sections titled: Introduction The Hammett Equation Substituent Effects on the Strengths of Carboxylic and Other Acids The Ortho-Effect The Cumulative Effects of Substituents Substituent Effects in Highly Electron-Demanding Reactions Electronic Effect of The Unipole O− The Impact of Modern Experimental and Theoretical Techniques on Substituent Constants Some Further Multiparameter Treatments of Substituent Effects Substituent Constants: Recapitulation and Some Extension References and Notes

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Available abstract

This chapter contains sections titled: Introduction The Hammett Equation Substituent Effects on the Strengths of Carboxylic and Other Acids The Ortho-Effect The Cumulative Effects of Substituents Substituent Effects in Highly Electron-Demanding Reactions Electronic Effect of The Unipole O− The Impact of Modern Experimental and Theoretical Techniques on Substituent Constants Some Further Multiparameter Treatments of Substituent Effects Substituent Constants: Recapitulation and Some Extension References and Notes

Key concepts: Substituent, Electronic effect, Chemistry, Ether, Hammett equation, Medicinal chemistry, Group (periodic table), Computational chemistry

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