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1990•Journal of the Chemical Society Chemical CommunicationsRequires access

Insertion of tellurium into an alkylpentacarbonylmanganese complex and a convenient new route to manganese telluride

Katherine McGregor, Glen B. Deacon, Ron S. Dickson, Gary D. Fallon, R.S. Rowe, Bruce O. West

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Abstract

The reaction between [Mn(Ch2Ph)(CO)5] and TePEt3 results in the insertion of tellurium into the Mn–CH2 bond, producing the first known monomeric σ-bonded alkyltelluriomanganese complex [Mn(TeCH2Ph)(CO)3(PEt3)2]2; pyrolysis of 2 yields polycrystalline manganese telluride.

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What this paper is about

The reaction between [Mn(Ch2Ph)(CO)5] and TePEt3 results in the insertion of tellurium into the Mn–CH2 bond, producing the first known monomeric σ-bonded alkyltelluriomanganese complex [Mn(TeCH2Ph)(CO)3(PEt3)2]2; pyrolysis of 2 yields polycrystalline manganese telluride.

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Available abstract

The reaction between [Mn(Ch2Ph)(CO)5] and TePEt3 results in the insertion of tellurium into the Mn–CH2 bond, producing the first known monomeric σ-bonded alkyltelluriomanganese complex [Mn(TeCH2Ph)(CO)3(PEt3)2]2; pyrolysis of 2 yields polycrystalline manganese telluride.

Key concepts: Tellurium, Telluride, Manganese, Chemistry, Chalcogen, Monomer, Inorganic chemistry, Crystallography

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