2009•Petroleum ChemistryRequires access

Effect of zinc-subgroup metal salts on the formation of hydroperoxide during the oxidation of cumene

Н. М. Нуруллина, Н Н Батыршин, Х. Э. Харлампиди

Abstract

The oxidation of cumene catalyzed by zinc, cadmium, and mercury 2-ethylhexanoates was studied. It was found that the catalytic effect weakens in the order Cd-Hg-Zn. The influence of an initiator on the cumene hydroperoxide buildup in the presence of group IIB metal compounds was revealed.

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Key concepts: Cumene, Cumene hydroperoxide, Zinc, Cadmium, Chemistry, Mercury (programming language), Metal, Catalysis