ScholarLens Back to search
2014•Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal ChemistryRequires access

A New Zn(II) Coordination Polymer With Helical Character: Synthesis and Crystal Structure

Hongliang Li

Open publisher page 0 citations

Abstract

A new Zn(II) coordination polymer with and has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR, and element analysis. Complex [Zn(bda)(bpa)]n (1) [H2bda = 2,4′-biphenyl-dicarboxylic acid, and bpa = bis(4-pyridyl)amine is monoclinic, space group P21/c with a = 16.518(5), b = 8.600 (5), c = 16.819 (5) Å, β = 115.318 (5)°, V = 2159.7 (16) Å3, Z = 4, Mr = 476.78, Dc = 1.466g/cm3, F(000) = 976, and μ = 1.173 mm−1. The final refinement gave R = 0.0355 and wR = 0.0670 for 2534 reflections with I > 2σ(I). X-ray diffraction analysis reveals that the complex 1 displays a two-dimensional structure with helical chain substructure.

About this research paper

What this paper is about

A new Zn(II) coordination polymer with and has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR, and element analysis. Complex [Zn(bda)(bpa)]n (1) [H2bda = 2,4′-biphenyl-dicarboxylic acid, and bpa = bis(4-pyridyl)amine is monoclinic, space group P21/c with a = 16.518(5), b = 8.600 (5), c = 16.819 (5) Å, β = 115.318 (5)°, V = 2159.7 (16) Å3, Z = 4, Mr = 476.78, Dc = 1.466g/cm3, F(000) = 976, and μ = 1.173 mm−1. The final refinement gave R = 0.0355 and wR = 0.0670 for 2534 reflections with I > 2σ(I). X-ray diffraction analysis reveals that the complex 1 displays a two-dimensional structure with helical chain substructure.

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

A new Zn(II) coordination polymer with and has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR, and element analysis. Complex [Zn(bda)(bpa)]n (1) [H2bda = 2,4′-biphenyl-dicarboxylic acid, and bpa = bis(4-pyridyl)amine is monoclinic, space group P21/c with a = 16.518(5), b = 8.600 (5), c = 16.819 (5) Å, β = 115.318 (5)°, V = 2159.7 (16) Å3, Z = 4, Mr = 476.78, Dc = 1.466g/cm3, F(000) = 976, and μ = 1.173 mm−1. The final refinement gave R = 0.0355 and wR = 0.0670 for 2534 reflections with I > 2σ(I). X-ray diffraction analysis reveals that the complex 1 displays a two-dimensional structure with helical chain substructure.

Key concepts: Monoclinic crystal system, Crystallography, Crystal structure, Hydrothermal synthesis, Substructure, Coordination polymer, Diffraction, Materials science

Related papers

Related paper 1Related paper 2Related paper 3
Back to paper searchBrowse research topicsOriginal source
A New Zn(II) Coordination Polymer With Helical Character: Synthesis and Crystal Structure — Research Paper | ScholarLens