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1974•Journal of the Chemical Society Chemical CommunicationsRequires access

The peroxo-group as a doubly bidentate bridging ligand in five-co-ordinate lanthanide complexes

D. C. Bradley, Joginder S. Ghotra, F. A. Hart, Michael B. Hursthouse, Paul R. Raithby

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Abstract

Reaction of OPPh3 with M{N(SiMe3)2}3(M = a lanthanide) yields complexes M2O2{N(SiMe3)2}4(OPPh3)2 which contain a doubly bidentate peroxo-group and 5-co-ordinate lanthanide ions.

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What this paper is about

Reaction of OPPh3 with M{N(SiMe3)2}3(M = a lanthanide) yields complexes M2O2{N(SiMe3)2}4(OPPh3)2 which contain a doubly bidentate peroxo-group and 5-co-ordinate lanthanide ions.

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OpenAlex reports 13 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

Reaction of OPPh3 with M{N(SiMe3)2}3(M = a lanthanide) yields complexes M2O2{N(SiMe3)2}4(OPPh3)2 which contain a doubly bidentate peroxo-group and 5-co-ordinate lanthanide ions.

Key concepts: Lanthanide, Denticity, Chemistry, Ion, Group (periodic table), Bridging (networking), Ligand (biochemistry), Stereochemistry

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