1977•Journal of the Chemical Society Perkin Transactions 2Requires access

Free radical adducts of tri(cyclohexyl)plumbyl radicals with α-dicarbonyl compounds

Andrew Hudson, Richard A. Jackson, N. P. C. SIMMONS

Abstract

The addition of lead-centred radicals to five α-dicarbonyl compounds has been investigated by e.s.r. In a number of cases satellite hyperfine lines from 207Pb have been detected. The structures of the adduct radicals are discussed in terms of their e.s.r. spectra; comparison is made with analogous adducts formed by other group 4B radicals.

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Key concepts: Radical, Adduct, Chemistry, Hyperfine structure, Photochemistry, Medicinal chemistry, Organic chemistry, Quantum mechanics