2010•Russian Journal of Physical Chemistry BRequires access

The solubility of styrene in supercritical carbon dioxide

А. Т. Тухватова, Rashit Abdulhakovich Kayumov, В. Ф. Хайрутдинов, А. А. Сагдеев, Н. Н. Саримов, Farid Mukhamedovich Gumerov, Farizan Rakibovich Gabitov, Svetoslav Isaakovich Volfson

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Abstract

Possible reasons for the existing differences in styrene solubilities in supercritical carbon dioxide obtained using the dynamic (flow) method are analyzed. The results of an experimental study of the solubility of styrene in supercritical CO 2 with the use of the static method of measurements and an improved dynamic cell are given. The influence of styrene polymerization under experimental conditions on measurement results at elevated pressures is analyzed. A mathematical formulation for the description of solubility data with the use of the Peng-Robinson equation and three adjustment parameters is presented. The experimental data on the solubility of styrene in supercritical carbon dioxide are described.

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What this paper is about

Possible reasons for the existing differences in styrene solubilities in supercritical carbon dioxide obtained using the dynamic (flow) method are analyzed. The results of an experimental study of the solubility of styrene in supercritical CO 2 with the use of the static method of measurements and an improved dynamic cell are given. The influence of styrene polymerization under experimental conditions on measurement results at elevated pressures is analyzed. A mathematical formulation for the description of solubility data with the use of the Peng-Robinson equation and three adjustment parameters is presented. The experimental data on the solubility of styrene in supercritical carbon dioxide are described.

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Available abstract

Possible reasons for the existing differences in styrene solubilities in supercritical carbon dioxide obtained using the dynamic (flow) method are analyzed. The results of an experimental study of the solubility of styrene in supercritical CO 2 with the use of the static method of measurements and an improved dynamic cell are given. The influence of styrene polymerization under experimental conditions on measurement results at elevated pressures is analyzed. A mathematical formulation for the description of solubility data with the use of the Peng-Robinson equation and three adjustment parameters is presented. The experimental data on the solubility of styrene in supercritical carbon dioxide are described.

Key concepts: Supercritical carbon dioxide, Styrene, Supercritical fluid, Solubility, Carbon dioxide, Materials science, Polymerization, Hildebrand solubility parameter

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