1994Journal of Physics B Atomic Molecular and Optical PhysicsOpen access

R-matrix study of the 6dng, 6dni and 7sni J=6 autoionizing Rydberg series of barium

M Aymar, E. Luc‐Koenig, J. M. Lecomte

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Abstract

The 6dng, 6dni and 7sni J=6 autoionizing Rydberg series of barium have been investigated using the eigenchannel R-matrix method together with multichannel quantum defect theory. For the 6dng and 6dni J=6 series, results concern the energy positions, autoionization widths and autoionization branching ratios as well as the perturbations of these series by 4fnl J=6 e levels. For the 7sni series, results restricted to the energy positions. The theoretical results are compared with recent experimental results and show good agreement for the 6dng and 7sni series. A possible explanation for the discrepancies between theory and experiment for 6dni series is proposed.

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The 6dng, 6dni and 7sni J=6 autoionizing Rydberg series of barium have been investigated using the eigenchannel R-matrix method together with multichannel quantum defect theory. For the 6dng and 6dni J=6 series, results concern the energy positions, autoionization widths and autoionization branching ratios as well as the perturbations of these series by 4fnl J=6 e levels. For the 7sni series, results restricted to the energy positions. The theoretical results are compared with recent experimental results and show good agreement for the 6dng and 7sni series. A possible explanation for the discrepancies between theory and experiment for 6dni series is proposed.

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Available abstract

The 6dng, 6dni and 7sni J=6 autoionizing Rydberg series of barium have been investigated using the eigenchannel R-matrix method together with multichannel quantum defect theory. For the 6dng and 6dni J=6 series, results concern the energy positions, autoionization widths and autoionization branching ratios as well as the perturbations of these series by 4fnl J=6 e levels. For the 7sni series, results restricted to the energy positions. The theoretical results are compared with recent experimental results and show good agreement for the 6dng and 7sni series. A possible explanation for the discrepancies between theory and experiment for 6dni series is proposed.

Key concepts: Autoionization, Rydberg formula, Physics, Quantum defect, Series (stratigraphy), Atomic physics, Barium, R-matrix

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