Pyroelectric properties in polar hemicyanine Langmuir-Blodgett multilayer films
Shihong Ma, Mei Yan, Wencheng Wang, Zhiming Zhang, Zhanghai Chen, Pulin Liu, Junhao Zhu, Cuifeng Qu, Shengwei Lin
Abstract
Shihong Ma, Mei Yan, Wencheng Wang, Zhiming Zhang, Zhanghai Chen, Pulin Liu, Junhao Zhu, Cuifeng Qu, Shengwei Lin
Abstract
The Langmuir-Blodgett (LB) films of hemocyanin dyes were prepared by LB technique. The films show pyroelectric effect. The pyroelectric coefficient measured by the method of integrated charges is 12 (mu) C m-2 K-1 at room temperature. The relationship between the orientation of DAEP in the films and temperature was studied by polarized FTIR spectroscopy and second-harmonic generation. The physical mechanism of pyroelectricity in the films was also discussed.
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The Langmuir-Blodgett (LB) films of hemocyanin dyes were prepared by LB technique. The films show pyroelectric effect. The pyroelectric coefficient measured by the method of integrated charges is 12 (mu) C m-2 K-1 at room temperature. The relationship between the orientation of DAEP in the films and temperature was studied by polarized FTIR spectroscopy and second-harmonic generation. The physical mechanism of pyroelectricity in the films was also discussed.
Key concepts: Pyroelectricity, Langmuir–Blodgett film, Polar, Materials science, Fourier transform infrared spectroscopy, Second-harmonic generation, Infrared spectroscopy, Analytical Chemistry (journal)