1996•Inorganic ChemistryRequires access
Synthesis and Structure of the First Stable Iminoarsane
Jens‐Thomas Ahlemann, Antje Künzel, Herbert W. Roesky, Mathias Noltemeyer, L. N. Markovskii, Hans‐Georg Schmidt
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Abstract
Reaction of 2,4,6-tris(trifluoromethyl)phenyldichloroarsane with potassium 2,4,6-tris(trifluoromethyl)anilide 1 yields As,N-bis(2,4,6-tris(trifluoromethyl)phenyl)iminoarsane, 3, and As,N,N‘-tris(2,4,6-tris(trifluoromethyl)phenyl)diaminoarsane, 4. The first X-ray structural analysis of a compound containing a CNAsC bonding unit shows the monomeric character of 3.