2013Journal of Vacuum Science & Technology B Nanotechnology and Microelectronics Materials Processing Measurement and PhenomenaRequires access

Field emission study of change in work function of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) film

Ying Xing, Min Fang Qian, Jing Fang Qin, Geng Min Zhang

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Abstract

Modification of the work function of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) was obtained by irradiating PEDOT:PSS film in vacuum with 254 nm ultraviolet (UV) light. Work function change was measured by a field emission technique in situ. A small increase in the work function was observed after a brief period of irradiation. When the irradiation time was prolonged, a monotonous reduction in the work function occurred in high vacuum. The effect of oxygen on UV-illuminated PEDOT:PSS was studied, and recovery of the work function was achieved after 3 h of oxygen exposure. The result shows that tuning the work function of PEDOT:PSS in the desired direction with UV treatment is possible.

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What this paper is about

Modification of the work function of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) was obtained by irradiating PEDOT:PSS film in vacuum with 254 nm ultraviolet (UV) light. Work function change was measured by a field emission technique in situ. A small increase in the work function was observed after a brief period of irradiation. When the irradiation time was prolonged, a monotonous reduction in the work function occurred in high vacuum. The effect of oxygen on UV-illuminated PEDOT:PSS was studied, and recovery of the work function was achieved after 3 h of oxygen exposure. The result shows that tuning the work function of PEDOT:PSS in the desired direction with UV treatment is possible.

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Available abstract

Modification of the work function of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) was obtained by irradiating PEDOT:PSS film in vacuum with 254 nm ultraviolet (UV) light. Work function change was measured by a field emission technique in situ. A small increase in the work function was observed after a brief period of irradiation. When the irradiation time was prolonged, a monotonous reduction in the work function occurred in high vacuum. The effect of oxygen on UV-illuminated PEDOT:PSS was studied, and recovery of the work function was achieved after 3 h of oxygen exposure. The result shows that tuning the work function of PEDOT:PSS in the desired direction with UV treatment is possible.

Key concepts: PEDOT:PSS, Work function, Materials science, Poly(3,4-ethylenedioxythiophene), Irradiation, Ultraviolet, Work (physics), Oxygen

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