Field emission study of change in work function of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) film
Ying Xing, Min Fang Qian, Jing Fang Qin, Geng Min Zhang
Abstract
Ying Xing, Min Fang Qian, Jing Fang Qin, Geng Min Zhang
Abstract
Modification of the work function of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) was obtained by irradiating PEDOT:PSS film in vacuum with 254 nm ultraviolet (UV) light. Work function change was measured by a field emission technique in situ. A small increase in the work function was observed after a brief period of irradiation. When the irradiation time was prolonged, a monotonous reduction in the work function occurred in high vacuum. The effect of oxygen on UV-illuminated PEDOT:PSS was studied, and recovery of the work function was achieved after 3 h of oxygen exposure. The result shows that tuning the work function of PEDOT:PSS in the desired direction with UV treatment is possible.
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Modification of the work function of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) was obtained by irradiating PEDOT:PSS film in vacuum with 254 nm ultraviolet (UV) light. Work function change was measured by a field emission technique in situ. A small increase in the work function was observed after a brief period of irradiation. When the irradiation time was prolonged, a monotonous reduction in the work function occurred in high vacuum. The effect of oxygen on UV-illuminated PEDOT:PSS was studied, and recovery of the work function was achieved after 3 h of oxygen exposure. The result shows that tuning the work function of PEDOT:PSS in the desired direction with UV treatment is possible.
Key concepts: PEDOT:PSS, Work function, Materials science, Poly(3,4-ethylenedioxythiophene), Irradiation, Ultraviolet, Work (physics), Oxygen