Extraction Equilibria of Succinic Acid from Aqueous Solutions by Amberlite LA-2 in Various Diluents
Yavuz Selim Aşçı, İsmail İncı̇
Abstract
Yavuz Selim Aşçı, İsmail İncı̇
Abstract
The aim of this study is to investigate the extraction of succinic acid from aqueous solutions by different organic solutions containing Amberlite LA-2, a secondary amine mixture. Extraction equilibria of succinic acid in the solution of Amberlite LA-2 in seven individual diluents at a temperature of 298.15 K have been measured. Using Bizek’s approach, two acid−amine complexes, (HO)·(R 2 N) and (HO)·(R 2 N) 2, are assumed to exist in the organic phase in the case of proton-donating diluents, while the complexes (HO)·(R 2 N) and (HO) 2 ·(R 2 N) 3 are suggested in the case of nonproton-donating diluents. Important data for the design of separation units have been obtained as a result of batch experiments. These data are distribution coefficients ( D ), loading factors ( Z ), extraction efficiencies ( E ), and overall extraction constants ( K 11, K 12, and K 23 ).
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The aim of this study is to investigate the extraction of succinic acid from aqueous solutions by different organic solutions containing Amberlite LA-2, a secondary amine mixture. Extraction equilibria of succinic acid in the solution of Amberlite LA-2 in seven individual diluents at a temperature of 298.15 K have been measured. Using Bizek’s approach, two acid−amine complexes, (HO)·(R 2 N) and (HO)·(R 2 N) 2, are assumed to exist in the organic phase in the case of proton-donating diluents, while the complexes (HO)·(R 2 N) and (HO) 2 ·(R 2 N) 3 are suggested in the case of nonproton-donating diluents. Important data for the design of separation units have been obtained as a result of batch experiments. These data are distribution coefficients ( D ), loading factors ( Z ), extraction efficiencies ( E ), and overall extraction constants ( K 11, K 12, and K 23 ).
Key concepts: Amberlite, Diluent, Chemistry, Extraction (chemistry), Amine gas treating, Succinic acid, Aqueous solution, Aqueous two-phase system