1996•Chemical CommunicationsRequires access

Reversibility in free-radical reactions of aryltellurides with tributylstannyl radical

Carl H. Schiesser, Melissa A. Skidmore

Abstract

119 Sn and 125Te NMR spectroscopies reveal that methyl, primary and secondary alkyl radicals, generated by reaction of phenyltelluroalkanes 4, 6, 7 with tributyltin hydride (benzene, AIBN initiator), are capable of displacing tributylstannyl radicals from (4-fluorophenyltelluro)tributylstannane to afford the 4-fluorophenyltelluroalkanes 3, 8, 9.

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Key concepts: Tributyltin hydride, Radical, Chemistry, Radical initiator, Alkyl, Primary (astronomy), Tributyltin, Benzene