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1965•Bulletin des Sociétés Chimiques BelgesRequires access

Electron Irradiation of Hydrocarbons. III. Radical Reactions and Diffusion During Radiolysis

P. Claes, Stefan J. Rzad

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Abstract

Abstract This work concerns the theoretical study of the influence of tracks expansion on radicals reactions occuring during the radiolysis of hydrocarbons. It is shown that a dose rate effect may occur on the organic products yields. This should be due to the competition between organic radicals recombination and hydrogen abstraction from the solvent by these radicals. Hydrogen atoms, however, react chiefly by hydrogen abstraction from the solvent.

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What this paper is about

Abstract This work concerns the theoretical study of the influence of tracks expansion on radicals reactions occuring during the radiolysis of hydrocarbons. It is shown that a dose rate effect may occur on the organic products yields. This should be due to the competition between organic radicals recombination and hydrogen abstraction from the solvent by these radicals. Hydrogen atoms, however, react chiefly by hydrogen abstraction from the solvent.

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Available abstract

Abstract This work concerns the theoretical study of the influence of tracks expansion on radicals reactions occuring during the radiolysis of hydrocarbons. It is shown that a dose rate effect may occur on the organic products yields. This should be due to the competition between organic radicals recombination and hydrogen abstraction from the solvent by these radicals. Hydrogen atoms, however, react chiefly by hydrogen abstraction from the solvent.

Key concepts: Radiolysis, Radical, Hydrogen atom abstraction, Photochemistry, Chemistry, Hydrogen, Solvent, Radiation chemistry

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