2002•Zeitschrift für anorganische und allgemeine ChemieRequires access

Photoinduced Isomerization of Potassium Polyfluoroalk-1-enyltrifluoroborates

Vadim V. Bardin, Hermann‐Josef Frohn

Abstract

The UV irradition of K [RCF=CFBF3] [R = C4F9 (trans), C2F5 (cis), C6F13 (cis), Cl (cis/trans 1 : 1)] in acetone led to cis/trans-isomerization with a final cis/trans composition 7 : 3. In the case of R = C4H9 (trans) or C3F7O (cis/trans 25 : 75) the photoisomerization was accompanied by a partial decomposition.

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Key concepts: Photoisomerization, Isomerization, Chemistry, Acetone, Cis–trans isomerism, Decomposition, Potassium, Photochemistry