2010•Dalton TransactionsRequires access

Addition of [(η5-C5Me5)IrH4] to a zwitterionic silylene: stepwise formation of iridium(v)-silyl and iridium(iii)-silylene complexes

A.-K. Jungton, Antje Meltzer, Carsten Präsang, Thomas Braun, Matthias Drieß, Anna Penner

Abstract

The first zwitterionic silyl-iridium(v) complex is generated by insertion of silylene into an iridium-hydrogen bond of the iridium(v) hydride , [(eta(5)-C(5)Me(5))IrH(4)]. Complex undergoes proton migration from an IrH moiety to the terminal CH(2) group of the silyl ligand to furnish the N-donor stabilised Ir(iii)-silylene complex .

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Key concepts: Iridium, Silylene, Silylation, Chemistry, Moiety, Hydride, Ligand (biochemistry), Photochemistry