2004•Unpublished venueRequires access

Catalytic Enantioselective Aldol Additions with Chiral Lewis Bases

Scott E. Denmark, Shinji Fujimori

Abstract

This chapter contains sections titled: Introduction Preparation of Enoxytrichlorosilanes Preparation of Chiral Lewis Bases Enantioselective Aldol Addition of Achiral Enoxytrichlorosilanes Diastereoselective Additions of Chiral Enoxytrichlorosilanes Aldol Additions of Aldehyde-derived Enoxytrichlorosilanes Aldol Addition of Trichlorosilyl Ketene Acetal to Aldehydes and Ketones Lewis Base Activation of Lewis Acids -Aldol Additions of Silyl Enol Ethers to Aldehydes Toward a United Mechanistic Scheme Conclusions and Outlook Representative Procedures

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Available abstract

Key concepts: Aldol reaction, Lewis acids and bases, Enantioselective synthesis, Ketene, Enol, Chemistry, Acetal, Silylation