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Analysis of Lignite Using Laser-Induced Breakdown Spectroscopy

Fiona J. Wallis, Bruce L. Chadwick, Richard J. S. Morrison

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Abstract

The application of laser-induced breakdown spectroscopy (LIBS) to the chemical analysis of low-ash lignite has been investigated. A Nd: YAG laser (λ = 1064 nm) is used to induce emission from the ash-forming components, which is then spectrally resolved and analyzed. LIBS analyses of five inorganic components of lignite were shown to be reproducible between sample pellets at a 95% confidence level. Detection limits (in ppm) on an as-received basis of 60 (Ca and Al), 70 (Na), 90 (Fe), and 200 (Mg and Si) were obtained from a study of 30 lignite samples, each of which was interrogated by 300 laser pulses.

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What this paper is about

The application of laser-induced breakdown spectroscopy (LIBS) to the chemical analysis of low-ash lignite has been investigated. A Nd: YAG laser (λ = 1064 nm) is used to induce emission from the ash-forming components, which is then spectrally resolved and analyzed. LIBS analyses of five inorganic components of lignite were shown to be reproducible between sample pellets at a 95% confidence level. Detection limits (in ppm) on an as-received basis of 60 (Ca and Al), 70 (Na), 90 (Fe), and 200 (Mg and Si) were obtained from a study of 30 lignite samples, each of which was interrogated by 300 laser pulses.

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OpenAlex reports 76 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

The application of laser-induced breakdown spectroscopy (LIBS) to the chemical analysis of low-ash lignite has been investigated. A Nd: YAG laser (λ = 1064 nm) is used to induce emission from the ash-forming components, which is then spectrally resolved and analyzed. LIBS analyses of five inorganic components of lignite were shown to be reproducible between sample pellets at a 95% confidence level. Detection limits (in ppm) on an as-received basis of 60 (Ca and Al), 70 (Na), 90 (Fe), and 200 (Mg and Si) were obtained from a study of 30 lignite samples, each of which was interrogated by 300 laser pulses.

Key concepts: Laser-induced breakdown spectroscopy, Pellets, Spectroscopy, Analytical Chemistry (journal), Laser, Materials science, Atomic emission spectroscopy, Chemistry

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