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1978•Bulletin of the Chemical Society of JapanOpen access

The Reaction of Ethylbenzene with Methylbenzene–AlCl3–HCl Complex

Nobuyoshi Nambu, Sawako Hamanaka, Masaya Ogawa

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Abstract

Abstract Toluene, m-xylene, and mesitylene complexes prepared with AlCl3 and HCl, were separated from the upper hydrocarbon layer and allowed to react with ethylbenzene at 2 and 30 °C. The proton exchange between methylbenzenium ions and ethylbenzene, and the transalkylation of ethylbenzene were investigated by 13C NMR spectroscopy.

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Abstract Toluene, m-xylene, and mesitylene complexes prepared with AlCl3 and HCl, were separated from the upper hydrocarbon layer and allowed to react with ethylbenzene at 2 and 30 °C. The proton exchange between methylbenzenium ions and ethylbenzene, and the transalkylation of ethylbenzene were investigated by 13C NMR spectroscopy.

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Available abstract

Abstract Toluene, m-xylene, and mesitylene complexes prepared with AlCl3 and HCl, were separated from the upper hydrocarbon layer and allowed to react with ethylbenzene at 2 and 30 °C. The proton exchange between methylbenzenium ions and ethylbenzene, and the transalkylation of ethylbenzene were investigated by 13C NMR spectroscopy.

Key concepts: Ethylbenzene, Mesitylene, Chemistry, Transalkylation, Toluene, Cyclohexanes, m-Xylene, Styrene

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