Tris(2-pyridyl)phosphine oxide: how C—H...O and C—H...N interactions can affect crystal packing efficiency
R.J. Bowen, Manuel Antonio Fernandes, Patricia W. Gitari, Marcus Layh
Abstract
R.J. Bowen, Manuel Antonio Fernandes, Patricia W. Gitari, Marcus Layh
Abstract
Tris(2-pyridyl)phosphine oxide, (I), C(15)H(12)N(3)OP, is isomorphous with tris(2-pyridyl)phosphine. Because of a combination of C-H.O and C-H.N interactions, the crystal packing is denser in the title compound than in the related compounds triphenylphosphine oxide and tris(2-pyridyl)phosphine.
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Tris(2-pyridyl)phosphine oxide, (I), C(15)H(12)N(3)OP, is isomorphous with tris(2-pyridyl)phosphine. Because of a combination of C-H.O and C-H.N interactions, the crystal packing is denser in the title compound than in the related compounds triphenylphosphine oxide and tris(2-pyridyl)phosphine.
Key concepts: Phosphine oxide, Tris, Phosphine, Oxide, Chemistry, Crystal (programming language), Crystal structure, Crystallography