Stereochemistry of olefin and fatty acid oxidation. Part 3. The allylic hydroperoxides from the autoxidation of methyl oleate
E. N. Frankel, R. F. Garwood, Bhupinder P. S. Khambay, Gerard P. Moss, B. C. L. Weedon
Abstract
E. N. Frankel, R. F. Garwood, Bhupinder P. S. Khambay, Gerard P. Moss, B. C. L. Weedon
Abstract
Methods have been developed, using 13C n.m.r. spectroscopy and mass spectrometry, for the analysis of all eight cis and trans allylic 8-, 9-, 10-, and 11-hydroperoxides formed on autoxidation of methyl oleate.
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Methods have been developed, using 13C n.m.r. spectroscopy and mass spectrometry, for the analysis of all eight cis and trans allylic 8-, 9-, 10-, and 11-hydroperoxides formed on autoxidation of methyl oleate.
Key concepts: Autoxidation, Allylic rearrangement, Chemistry, Methyl oleate, Mass spectrometry, Olefin fiber, Organic chemistry, Fatty acid