Electrochemical synthesis of heterocyclic compounds. XII. Anodic oxidation of catechol in the presence of nucleophiles
Ibro Tabaković, Z. GRUJIC, Zlatko Bejtović
Abstract
Ibro Tabaković, Z. GRUJIC, Zlatko Bejtović
Abstract
Abstract The electrochemical synthesis of coumestan derivatives and some related heterocyclic system (2a‐11a) by anodic oxidation of catechol (1) in the presence of various nucleophiles 2‐11 is described. Products were obtained in good yields and purity. The mechanism of oxidation was deduced from voltammetric data and by coulometry at controlled potential.
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Abstract The electrochemical synthesis of coumestan derivatives and some related heterocyclic system (2a‐11a) by anodic oxidation of catechol (1) in the presence of various nucleophiles 2‐11 is described. Products were obtained in good yields and purity. The mechanism of oxidation was deduced from voltammetric data and by coulometry at controlled potential.
Key concepts: Chemistry, Catechol, Coulometry, Nucleophile, Electrochemistry, Anodic oxidation, Anode, Cyclic voltammetry