The reaction of ketene silyl acetals and silyl enol ethers with CCl4 without a promoter
Michiharu Mitani, Hideo Sakata
Abstract
Michiharu Mitani, Hideo Sakata
Abstract
The reaction of CCl4 with ketene silyl acetals and silyl enol ethers in the absence of a promoter at ambient temperature or at reflux, or under photo-irradiation, was performed to form products via addition of the trichloromethyl group to those silyl substrates.
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The reaction of CCl4 with ketene silyl acetals and silyl enol ethers in the absence of a promoter at ambient temperature or at reflux, or under photo-irradiation, was performed to form products via addition of the trichloromethyl group to those silyl substrates.
Key concepts: Silylation, Ketene, Enol, Chemistry, Acetal, Organic chemistry, Medicinal chemistry, Photochemistry