1998Chemical CommunicationsRequires access

The reaction of ketene silyl acetals and silyl enol ethers with CCl4 without a promoter

Michiharu Mitani, Hideo Sakata

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Abstract

The reaction of CCl4 with ketene silyl acetals and silyl enol ethers in the absence of a promoter at ambient temperature or at reflux, or under photo-irradiation, was performed to form products via addition of the trichloromethyl group to those silyl substrates.

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What this paper is about

The reaction of CCl4 with ketene silyl acetals and silyl enol ethers in the absence of a promoter at ambient temperature or at reflux, or under photo-irradiation, was performed to form products via addition of the trichloromethyl group to those silyl substrates.

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Available abstract

The reaction of CCl4 with ketene silyl acetals and silyl enol ethers in the absence of a promoter at ambient temperature or at reflux, or under photo-irradiation, was performed to form products via addition of the trichloromethyl group to those silyl substrates.

Key concepts: Silylation, Ketene, Enol, Chemistry, Acetal, Organic chemistry, Medicinal chemistry, Photochemistry

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