2012•The Journal of Organic ChemistryRequires access

Hetaryl-Substituted Phosphonium-Iodonium Ylides in Synthesis of Heterocycles

E. D. Matveeva, Tatyana A. Podrugina, Marina A. Taranova, M. Ivanova Anastasiya, Rolf Gleiter, Nikolay S. Zefirov

Abstract

A series of hitherto unknown hetaryl-substituted (in phosphonium part) phosphonium-iodonium ylides were synthesized. The reaction of these mixed phosphonium-iodonium ylides with acetylenes opens a way to new furyl annelated phosphinolines or unusually substituted phosphininofurans.

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Key concepts: Phosphonium, Chemistry, Medicinal chemistry, Combinatorial chemistry, Organic chemistry