2012Chemical and Pharmaceutical BulletinOpen access

Synthesis of Marine Diterpene Isocyanide (−)-Kalihinol Y and Diterpene Isothiocyanate (−)-10-Epi-kalihinol I

Hiroaki Miyaoka, Yasunori Abe, Etsuko Kawashima

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Abstract

The authors described the first synthesis of diterpene isocyanide (-)-kalihinol Y and diterpene isothiocyanate (-)-10-epi-kalihinol I from synthetic intermediates of kalihinol A. The absolute structures of these compounds were confirmed by these syntheses.

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The authors described the first synthesis of diterpene isocyanide (-)-kalihinol Y and diterpene isothiocyanate (-)-10-epi-kalihinol I from synthetic intermediates of kalihinol A. The absolute structures of these compounds were confirmed by these syntheses.

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Available abstract

The authors described the first synthesis of diterpene isocyanide (-)-kalihinol Y and diterpene isothiocyanate (-)-10-epi-kalihinol I from synthetic intermediates of kalihinol A. The absolute structures of these compounds were confirmed by these syntheses.

Key concepts: Diterpene, Chemistry, Isocyanide, Isothiocyanate, Stereochemistry, Organic chemistry

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