2012•High Energy ChemistryRequires access

Radiation-chemical synthesis of tetrafluoroethylene telomers in chloropentafluorobenzene and perfluoroxylene

G. A. Kichigina, P. P. Kushch, Dmitrii Pavlovich Kiryukhin

Abstract

The kinetics of radiation-induced telomerization of tetrafluoroethylene in chloropentafluorobenzene and perfluoroxylene have been studied. Colloidal solutions of thermally stable tetrafluoroethylene telomers with a chain length of 50–160 units have been obtained. A comparative analysis of the reactivity of some monohalogenated benzene derivatives used as telogens has been performed.

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Key concepts: Tetrafluoroethylene, Telomerization, Chemistry, Benzene, Reactivity (psychology), Polymer chemistry, Kinetics, Benzene derivatives